By Julio de Paula Peter Atkins
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Volume 1: Thermodynamics and Kinetics; ISBN 1-4292-3127-0
Volume 2: Quantum Chemistry, Spectroscopy, and Statistical Thermodynamics; ISBN 1-4292-3126-2
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Extra resources for Atkins' Physical chemistry
B) The wave is shown travelling to the right at a speed c. At a given location, the instantaneous amplitude of the wave changes through a complete cycle (the six dots show half a cycle) as it passes a given point. The frequency, ν, is the number of cycles per second that occur at a given point. Wavelength and frequency are related by λν = c. Fig. 8 A note on good practice You will hear people speaking of ‘a frequency of so many wavenumbers’. That is doubly wrong. First, wavenumber and frequency are two different physical observables.
1) Exercises Problems 20 1 THE PROPERTIES OF GASES This equation tells us that, if we know the values of n, T, and V for a particular substance, then the pressure has a ﬁxed value. Each substance is described by its own equation of state, but we know the explicit form of the equation in only a few special cases. 3). Much of the rest of this chapter will examine the origin of this equation of state and its applications. (a) Pressure Pressure, p, is deﬁned as force, F, divided by the area, A, to which the force is applied: p= Movable wall High pressure Low pressure (a) Equal pressures Equal pressures Low pressure High pressure (b) (c) When a region of high pressure is separated from a region of low pressure by a movable wall, the wall will be pushed into one region or the other, as in (a) and (c).
The structures show the bonding patterns and lone pairs and, except in simple cases, do not express the shape of the species. Fig. 1 3 4 FUNDAMENTALS Linear The names of the shapes of the geometrical ﬁgures used to describe symmetrical polyatomic molecules and ions. Angular Trigonal planar Tetrahedral Square planar Trigonal bipyramidal Octahedral Fig. 2 (a) (b) (a) The inﬂuences on the shape of the SF4 molecule according to the VSEPR model. (b) As a result the molecule adopts a bent see-saw shape.